- Combine 1½ teaspoons paprika, 1 teaspoon table salt, ½ teaspoon pepper, ½ teaspoon dried thyme, ½ teaspoon dried oregano, ½ teaspoon garlic powder, and ⅛ teaspoon cayenne in large bowl. Use paper towels to pat dry 1½ pounds extra-large shrimp (peeled, deveined, and tails removed), then add to bowl with spice mixture and toss to coat.
- Heat 12-inch cast-iron skillet over medium heat for 3 minutes. Add 1 tablespoon unsalted butter, swirling to melt. Once butter is melted, add 12 ounces grape tomatoes and cook, stirring occasionally, until charred in spots, about 2 minutes. Remove from heat, cover skillet, and let sit until tomatoes are softened, about 2 minutes. Transfer to medium bowl.
- Wipe out skillet with paper towels. Melt 1 tablespoon unsalted butter in now-empty skillet over medium heat, swirling to coat pan bottom. Add 2 cups corn and cook, stirring occasionally, until kernels are just beginning to soften, about 2 minutes. Cover skillet and cook, stirring occasionally, until softened, about 2 minutes. Add to bowl with tomatoes. Stir in 1 tablespoon chopped fresh basil, 1 tablespoon minced fresh chives, and remaining ½ teaspoon table salt.
- Wipe out skillet with paper towels. Melt remaining 1 tablespoon unsalted butter over medium-high heat, swirling to coat pan bottom, then add shrimp in single layer (shrimp may fit snugly at first but will shrink as they cook). Cook until opaque throughout, 1 to 2 minutes per side. Transfer shrimp to platter and sprinkle with remaining 1 tablespoon minced fresh chives. Serve with corn and blistered tomatoes.
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